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Silly String. It’s awesome for pranks or party shenanigans, but this foam could also save your life someday.

Hosted by: Michael Aranda
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Sources:
http://cen.acs.org/articles/87/i43/Silly-String.html
https://www.britannica.com/science/surfactant
https://www.wired.com/2015/10/whats-inside-silly-string/
https://www.whysprayfoam.org/what-is-spray-foam/
http://www.cbsnews.com/news/a-serious-use-for-silly-string/
https://dii.americanchemistry.com/Diisocyanates-Explained/What-Are-Diisocyanates/
https://www.epa.gov/saferchoice/chemicals-and-production-spray-polyurethane-foam-why-it-matters
http://www.lsta.lt/files/events/28_jarfelt.pdf
http://www.azom.com/article.aspx?ArticleID=8097
http://www.metalfoam.net/
http://www.fuelcellmarkets.com/content/images/articles/white_paper1.pdf
https://www.youtube.com/watch?v=ZcE-Hhtynf0
http://www.azom.com/article.aspx?ArticleID=10529
http://energy.gov/energysaver/insulation-materials
http://arris.partners/news/3-uses-metal-foam-arent-armor/
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https://www.jim.or.jp/journal/e/pdf3/52/04/728.pdf
http://www.sciencedirect.com/science/article/pii/S0263822315000434

Images:
https://commons.wikimedia.org/wiki/File%3ASilly_string.jpg
https://commons.wikimedia.org/wiki/File%3AGuesnain_(10_mai_2009)_parade_030.jpg
https://commons.wikimedia.org/wiki/File%3AU.S._Marine_Corps_instructors%2C_top%2C_with_the_2nd_Combat_Engineer_Battalion%2C_watch_as_Marines_with_Kilo_Company%2C_3rd_Battalion%2C_4th_Marine_Regiment_check_for_trip_wires_during_counter_improvised_explosive_device_130402-M-RF397-076.jpg
https://commons.wikimedia.org/wiki/File%3AAluminium_foam.jpg
By Stehfun (Own work) [GFDL (http://www.gnu.org/copyleft/fdl.html)
Michael: Ah, foam. Its frothy goodness is responsible for everything from shaving cream to lattes. But the word “foam” can describe any liquid or solid with tiny pockets of gas inside.

Think back to when you were a kid – maybe you blew bubbles in your milk. Those air-filled suds are a kind of foam, but so is a squishy memory foam mattress. Thanks to the gases inside, foams can be really lightweight, useful materials for lots of different purposes. They could even save your life someday.

Take Silly String. It’s awesome for pranks or party shenanigans, but there’s a lot of interesting chemistry going on inside these cans. The string part of this foamy toy is mostly made of an acrylic resin, a bunch of plastic molecules linked up in long chains. The original formula for Silly String had an acrylic resin called polyisobutyl methacrylate, which is also found in Plexiglass. This resin is mixed with a few other chemicals to give the strand some color, stickiness, and more strength.

Now, the propellant is what forces all this stuff out when you squeeze the ­nozzle of the can. This lets the pressure drop inside the can, so the compressed liquid propellant turns back into a gas, expanding to force the string goop out.

In the 1970s, Silly String used the ozone-depleting Freon-12 as a propellant, before chlorofluorocarbon gases were banned from production. Modern Silly String uses propellants called hydrofluorocarbons instead, which are cousins that don’t damage the ozone layer, but are still potent greenhouse gases.

Squeezing out this mixture of ingredients creates thin foamy strands, with lots of help from surfactants. Surfactants are molecules that can be found in detergents around your home.

They have water-loving hydrophilic end, which interact with water molecules, and awater-repelling hydrophobic end, which interact with other molecules like the ones in air or oil. So, when the Silly String liquid gets exposed to air, surfactants like sorbitan trioleate basically stabilize the bubbles of air inside to make a fluffy, sticky foam.

It’s a fun and messy toy for kids, but this lightweight foam also has been used for serious safety by the U.S. military – to detect trip wires near explosives. If they spray Silly String into an empty room, and it falls to the ground, the room is safe. But if there’s a trip wire or another hazard, the foam will hang off of it without setting off the booby trap.

Another cool sometimes-canned foam is spray foam insulation, also called spray polyurethane foam, or SPF for short. It’s that whitish-yellowish stuff that you might see in houses under construction, or even just in your garage. And it’s designed to expand and harden to control heat and airflow.

To make this foam, two separate mixtures are combined and sprayed at the exact same time. One container, usually called side A, contains some of the chemical building blocks of polyurethane, the polymer SPF is named after. They’re called isocyanates, which are a kind of organic chemical that all share a functional group of reactive atoms. And they’re used in lots of coatings, glues, and foams.

Side B stores the other building blocks called polyols, which have a bunch of hydroxyl functional groups. Side B has some other stuff in it too, like fireproofing chemicals, catalysts to speed up the reaction, surfactants, and a blowing agent, which helps expand the foam and affects its density and stiffness.

When sprayed, the A and B sides mix together to create the super-tough polyurethane polymers and some gases, to make a foam that hardens where it lands. The mixture of gases in the foam bubbles makes it resist heat transfer really well.

So when you spray this foam onto walls and roofs, it acts as an insulator and reduces unwanted airflow. It’s good for weatherproofing and it brings down the energy bill, which is never a bad thing! Finally, there’s the futuristic-sounding metal foam, which is just a solid metal — usually something like aluminum — with lots of gas-filled pores.

There are a couple ways to make it. You can inject some air, nitrogen, or argon gas straight into molten metal, creating gas bubbles as the metal expands, cools, and hardens. Or you can mix some blowing agents, like titanium hydride or calcium carbonate, into molten metal.

These chemicals decompose when they’re heated, which also makes bubbles. Metal foam is really useful because it acts just like its parent metal – with things like corrosion resistance, strength, electrical conductivity, and thermal conductivity – but at a fraction of the weight. So it can be used for lots of things.

For example, car parts made of metal foam cut down on noise, reduce weight, and can increase energy absorption during crashes so that we don’t get smushed. It’s been used to create lighter animal prosthetics. And, researchers are developing metal foam that mimics bone for biomedical implants that hopefully won’t be rejected by the human body.

There’s even research into composite metal foam, which combines several metals for even more strength, and could be developed into bulletproof armor. So foam’s not only for parties. It can save lives!

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